Dennis Hetterscheid
Associate professor
- Naam
- Dr. D.G.H. Hetterscheid
- Telefoon
- +31 71 527 4545
- d.g.h.hetterscheid@chem.leidenuniv.nl
- ORCID iD
- 0000-0001-5640-4416
Meer informatie is beschikbaar op de Engelse profielpagina.
Promovendi
Nieuws
-
Vernuftig experiment legt eindelijk bloot hoe goud water oxideert -
Twee Proof of Concept-subsidies naar Leiden -
Dana Rademaker blinkt uit en wint Unilever Research Prize -
Leidse chemici ontdekken ongekend efficiënte katalysator -
Leidse chemici ontvangen twee NWO-subsidies voor onderzoek naar duurzame materialen -
Op zoek naar duurzame energiebronnen -
ERC Starting Grant voor chemicus Dennis Hetterscheid -
Ruim een miljoen voor Leids excellent onderzoek chemie -
Leidse chemici ontvangen financiering voor onderzoek naar CO2-neutrale brandstoffen
Oud-promovendi
Associate professor
- Wiskunde en Natuurwetenschappen
- Leiden Institute of Chemistry
- LIC/Energy & Sustainability
- Rademaker D., Tanase S., Kang H., Hofmann J.P. & Hetterscheid D.G.H. (2024), Selective electrochemical oxygen reduction to hydrogen peroxide by confinement of cobalt porphyrins in a metal-organic framework, Chemistry - A European Journal 30(45): e202401339.
- Jeuken L.J.C., Hetterscheid D.G.H., Koper M.T.M., Casadevall C., Léger C., Llobet A., Milton R.D., Nakamura R. & Tschulik K. (2024), Toward an informative comparison of heterogeneous, synthetic, and biological electrocatalysis in energy conversion, Chem Catalysis : 101098.
- Langevelde P.H. van & Hetterscheid D.G.H. (2024), Selective electrochemical H2O2 production by a molecular copper catalyst: a crucial relation between reaction rate and mass transport, Chem Catalysis 4(8): 101069.
- Langevelde P.H. van, Kounalis E., Killian L., Monkcom E.C., Broere D.L.J. & Hetterscheid D.G.H. (2023), Mechanistic investigations into the selective reduction of oxygen by a multicopper oxidase T3 site-inspired dicopper complex, ACS Catalysis 13(8): 5712-5722.
- Langevelde P.H. van, Engbers S., Buda F. & Hetterscheid D.G.H. (2023), Elucidation of the electrocatalytic nitrite reduction mechanism by bio-inspired copper complexes, ACS Catalysis 13(15): 10094-10103.
- Hoefnagel M.E., Rademaker D. & Hetterscheid D.G.H. (2023), Directing the selectivity of oxygen reduction to water by confining a Cu catalyst in a metal organic framework, ChemSusChem 16(20): e202300392.
- Langerman M., Dorth M. van & Hetterscheid D.G.H. (2023), Dioxygen reduction in acetonitrile with copper pyridylalkylamine complexes: the influence of acid strength on the catalytic performance, European Journal of Inorganic Chemistry 26(24): e202300218.
- Boer D. den, Konovalov A., Siegler M.A. & Hetterscheid D.G.H. (2023), Unusual water oxidation mechanism via a redox-active copper polypyridyl complex, Inorganic Chemistry 62(14): 5303-5314.
- Budhija V., Langevelde P.H. van, Krause K.B., Cula B., Hetterscheid D.G.H. & Schwalbe M. (2023), Synthesis, properties and reactivity studies of a hetero‐dicopper complex consisting of a porphyrin and a bispyridylamine moiety connected by a xanthene backbone, European Journal of Inorganic Chemistry 26(14): e202200743.
- Langerman M., Langevelde P.H. van, Vijver J.J. van de & Siegler M.A. Hetterscheid D.G.H. (2023), Scaling relation between the reduction potential of copper catalysts and the turnover frequency for the oxygen and hydrogen peroxide reduction reactions, Inorganic Chemistry 62(48): 19593-19602.
- Wu X.F., Oropeza F.E., Boer D. den, Kleinschmidt P., Hannappel T., Hetterscheid D.G.H., Hensen E.J.M. & Hofmann J.P. (2023), Thermally induced oxygen vacancies in BiOCl nanosheets and their impact on photoelectrochemical performance, ChemPhotoChem 7(3): e202200192.
- Jiang L., Dijk van B., Wu L., Maheu C., Hofmann J.P., Tudor V., Koper M.T.M., Hetterscheid D.G.H. & Schneider G.F. (2022), Predoped oxygenated defects activate nitrogen-doped graphene for the oxygen reduction reaction, ACS Catalysis 12: 173-182.
- Boer D. den, Heer H.C. de, Buda F. & Hetterscheid D.G.H. (2022), Challenges in elucidating the free energy scheme of the laccase catalyzed reduction of oxygen, ChemCatChem 15(1): e202200878.
- Boer D. den, Siberie Q., Siegler M.A., Ferber T.H., Moritz D.C., Hofmann J.P. & Hetterscheid D.G.H. (2022), On the homogeneity of a cobalt-based water oxidation catalyst, ACS Catalysis 12(8): 4597-4607.
- Ham C.J.M. van der, Zwagerman D.N.H., Wu L., Hofmann J.P. & Hetterscheid D.G.H. (2022), A heterogenized copper phenanthroline system to catalyze the oxygen reduction reaction, ChemElectroChem 9(3): e202101365.
- Dijk B. van, Kinders R., Ferber T.H., Hofmann J.P. & Hetterscheid D.G.H. (2022), A selective copper based oxygen reduction catalyst for the electrochemical synthesis of H2O2 at neutral pH, ChemElectroChem 9(3): e202101692.
- Smits N.W.G., Rademaker D., Konovalov A.I., Siegler M.A. & Hetterscheid D.G.H. (2022), Influence of the spatial distribution of copper sites on the selectivity of the oxygen reduction reaction, Dalton Transactions 51(3): 1206-1215.
- Boer D. den & Hetterscheid D.G.H. (2022), Design principles for homogeneous water oxidation catalysts based on first–row transition metals, Current Opinion in Electrochemistry 35: 101064 (101064).
- D'Agostini S., Kottrup K.G., Casadevall C., Gamba I., Dantignana V., Bucci A., Costas M., Lloret-Fillol J. & Hetterscheid D.G.H. (2021), Electrocatalytic water oxidation with alpha-[Fe(mcp)(OTf)(2)] and analogues, ACS Catalysis 11(5): 2583-2595.
- Langerman M. & Hetterscheid D.G.H. (2021), Mechanistic study of the activation and the electrocatalytic reduction of hydrogen peroxide by Cu-tmpa in neutral aqueous solution, ChemElectroChem 8(15): 2783 –2791.
- Olivares M., Ham C.J.M. van der, Mdluli V., Schmidtendorf M., Müller-Bunz H., Verhoeven T.W.G.M., Li M., Niemantsverdriet J.W., Hetterscheid D.G.H., Bernhard S. & Albrecht M. (2020), Relevance of Chemical vs. Electrochemical Oxidation of Tunable Carbene Iridium Complexes for Catalytic Water Oxidation, European Journal of Inorganic Chemistry 2020(10): 801-812.
- Van Dijk B., Rodriguez G.M., Wu L., Hofmann J.P., Macchioni A. & Hetterscheid D.G.H. (2020), The influence of the ligand in the iridium mediated electrocatalyic water oxidation, ACS Catalysis 10(7): 4398-4410.
- Wu L., Dzade N.Y., Chen N., Dijk B. van, Balasubramanyam S., Sharma A., Gao Lu., Hetterscheid D.G.H., Hensen E.J.M., Bol A.A., Leeuw N.H. de & Hofmann J.P. (2020), Cu electrodeposition on nanostructured MoS2 and WS2 and implications for HER active site determination, Journal of The Electrochemical Society 167(11): 116517.
- Yang S. & Hetterscheid D.G.H. (2020), Redefinition of the active species and the mechanism of the oxygen evolution reaction on gold oxide, ACS Catalysis 10(21): 12582-12589.
- Smits N.W.G., Dijk B. van, Bruin I. de, Groeneveld S.L.T., Siegler M.A. & Hetterscheid D.G.H. (2020), Influence of ligand denticity and flexibility on the molecular copper mediated oxygen reduction reaction, Inorganic Chemistry 59(22): 16398-16409.
- Smits N.W.G., Boer D. den, Wu L., Hofmann J.P. & Hetterscheid D.G.H. (2019), Elucidation of the Structure of a Thiol Functionalized Cu-tmpa Complex Anchored to Gold via a Self-Assembled Monolayer, Inorganic Chemistry 58(19): 13007-13019.
- Langerman M. & Hetterscheid D.G.H. (2019), Fast Oxygen Reduction Catalyzed by a Copper(II) Tris(2-pyridylmethyl)amine Complex through a Stepwise Mechanism, Angewandte Chemie (International Edition) 58(37): 12974-12978.
- Kottrup K.G., D'Agostini S., Langevelde P.H. van, Siegler M.A. & Hetterscheid D.G.H. (2018), Catalytic Activity of an Iron-Based Water Oxidation Catalyst: Substrate Effects of Graphitic Electrodes, ACS Catalysis 8(2): 1052-1061.
- Dijk B. van, Hofmann J.P. & Hetterscheid D.G.H. (2018), Pinpointing the active species of the Cu(DAT) catalyzed oxygen reduction reaction, Physical Chemistry Chemical Physics 20: 19625-19634.
- Ham C.J.M. van der, Isik F., Verhoeven T.W.G.M., Niemantsverdriet J.W. & Hetterscheid D.G.H. (2017), Activation pathways taking place at molecular copper precatalysts for the oxygen evolution reaction, Catalysis Today 290: 33-38.
- Hetterscheid D.G.H. & Smith W.A. (red.) (2017), Electrochemical and photochemical water oxidation. Catalysis Today: Elsevier B.V..
- Hetterscheid D.G.H. (2017), In operando studies on the electrochemical oxidation of water mediated by molecular catalysts, Chemical Communications 53(77): 10622-10631.
- Ruiter J.M. de, Purchase R.L., Monti A., Ham C.J.M. van der, Gullo M.P., Joya K.S., D'Angelantonio M., Barbieri A., Hetterscheid D.G.H., Groot H.J.M. de & Buda F. (2016), Electrochemical and Spectroscopic Study of Mononuclear Ruthenium Water Oxidation Catalysts: A Combined Experimental and Theoretical Investigation, ACS Catalysis 6(11): 7340-7349.
- Hetterscheid D.G.H., Ham C.J. van der, Diaz Morales O.A., Verhoeven M.W.G.M., Longo A., Banerjee D., Niemantsverdriet J.W., Reek J.N.H. & Feiters M.C. (2016), Early stages of catalyst aging in the iridium mediated water oxidation reaction, Physical Chemistry Chemical Physics 18(16): 10931-10940.
- Abril P., Rio M.P. del, Tejel C., Verhoeven T.W.G.M., Niemantsverdriet J.W., Ham C.J.M., Kottrup K.G. & Hetterscheid D.G.H. (2016), Detangling catalyst modification reactions from the oxygen evolution reaction by online mass spectrometry, ACS Catalysis 6(11): 7872-7875.
- Kottrup K.G. & Hetterscheid D.G.H. (2016), Evaluation of iron-based electrocatalysts for water oxidation : an on-line mass spectrometry approach, Chemical Communications 52(12): 2643-2646.
- Chen H.C., Hetterscheid D.G.H., Williams R.M., Vlugt J.I. van der, Reek J.N.H. & Brouwer A.M. (2015), Platinum(II)-porphyrin as a sensitizer for visible-light driven water oxidation in neutral phosphate buffer, Energy & Environmental Science 8(3): 975-982.
- Hetterscheid D.G.H. & Sun Licheng (2014), Water Oxidation, European Journal of Inorganic Chemistry (4): 571-572.
- Ham C.J.M. van der, Koper M.T.M. & Hetterscheid D.G.H. (2014), Challenges in reduction of dinitrogen by proton and electron transfer, Chemical Society Reviews 43(15): 5183-5191.
- Venturini A., Barbieri A., Reek J.N.H. & Hetterscheid D.G.H. (2014), Catalytic water splitting with an iridium carbene complex: a theoretical study, Chemistry: a European Journal 20(18): 5358-5368.
- Diaz Morales O., Hersbach T.J.P., Hetterscheid D.G.H., Reek J.N.H. & Koper M.T.M. (2014), Electrochemical and spectroelectrochemical characterization of an iridium-based molecular catalyst for water splitting: turnover frequencies, stability, and electrolyte effects, Journal of the American Chemical Society 136(29): 10432-10439.
- Hetterscheid D.G.H. & Reek J.N.H. (2014), Periodate as an oxidant for catalytic water oxidation: oxidation via electron transfer or O-atom transfer?, European Journal of Inorganic Chemistry 2014(4): 742-749.
- Hetterscheid D.G.H., Chikkali S.H., Bruin B. de & Reek J.N.H. (2013), Binuclear Cooperative Catalysts for the Hydrogenation and Hydroformylation of Olefins, ChemCatChem 5(10): 2785-2793.
- Hetterscheid D.G.H. & Reek J.N.H. (2012), Mononuclear Water Oxidation Catalysts, Angewandte Chemie (International Edition) 51(39): 9740-9747.
- Tejel C., Pilar del Rio M., Asensio L., Bruele F.J. van den, Ciriano M.A., Tsichlis i Spithas N., Hetterscheid D.G.H. & Bruin B. de (2011), Cooperative Double Deprotonation of Bis(2-picolyl)amine Leading to Unexpected Bimetallic Mixed Valence (M-1, M-1) Rhodium and Iridium Complexes, Inorganic Chemistry 50(16): 7524-7534.
- Dzik W.I., Calvo S.E., Reek J.N.H., Lutz M., Ciriano M.A., Tejel C., Hetterscheid D.G.H. & Bruin B. de (2011), Binuclear [(cod)(Cl)Ir(bpi)Ir(cod)](+) for Catalytic Water Oxidation, Organometallics 30(3): 372-374.
- Hetterscheid D.G.H. & Reek J.N.H. (2011), Me-2-NHC based robust Ir catalyst for efficient water oxidation, Chemical Communications 47(9): 2712-2714.
- Kinney R.A., Hetterscheid D.G.H., Hanna B.S., Schrock R.R. & Hoffman B.M. (2010), Formation of {[HIPTN3N]Mo(III)H}(-) by Heterolytic Cleavage of H-2 as Established by EPR and ENDOR Spectroscopy, Inorganic Chemistry 49(2): 704-713.
- Tejel C., Pilar del Rio M., Ciriano M.A., Reijerse E.J., Hartl F., Zalis S., Hetterscheid D.G.H., Tsichlis i Spithas N. & Bruin B. de (2009), Ligand-Centred Reactivity of Bis(picolyl)amine Iridium: Sequential Deprotonation, Oxidation and Oxygenation of a "Non-Innocent" Ligand, Chemistry: a European Journal 15(44): 11878-11889.
- Hetterscheid D.G.H., Hanna B.S. & Schrock R.R. (2009), Molybdenum Triamidoamine Systems. Reactions Involving Dihydrogen Relevant to Catalytic Reduction of Dinitrogen, Inorganic Chemistry 48(17): 8569-8577.
- Hetterscheid D.G.H., Vlugt J.I. van der, Bruin B. de & Reek J.N.H. (2009), Water Splitting by Cooperative Catalysis, Angewandte Chemie (International Edition) 48(44): 8178-8181.
- Tejel C., Ciriano M.A., Pilar del Rio M., Hetterscheid D.G.H., Tsichlis i Spithas N., Smits J.M.M. & Bruin B. de (2008), Ligand Oxidation of a Deprotonated Bis(picolyl)amine Ir-I(cod) Complex, Chemistry: a European Journal 14(35): 10932-10936.
- Tejel C., Ciriano M.A., Del Rio M. Pilar, Bruele F.J. van den, Hetterscheid D.G.H., Spithas Nearchos Tsichlis I. & Bruin B. de (2008), Deprotonation induced ligand-to-metal electron transfer: Synthesis of a mixed-valence Rh(-I,I) dnuclear compound and its reaction with dioxygen, Journal of the American Chemical Society 130(18): 5844-5845.
- Bruin B. de & Hetterscheid D.G.H. (2007), Paramagnetic (alkene)Rh and (alkene)Ir complexes: Metal or ligand radicals?, European Journal of Inorganic Chemistry (2): 211-230.
- Hetterscheid D.G.H., Mop M., Kicken R.J.N.A.M., Smits J.M.M., Reijerse E.J. & Bruin B. de (2007), Hydrogen-atom transfer in open-shell organometallic chemistry: The reactivity of Rh-II(cod) and Ir-II(cod) radicals, Chemistry: a European Journal 13(12): 3386-3405.
- Bruin B. de, Hetterscheid D.G.H., Koekkoek A.J.J. & Gruetzmacher H. (2007), The Organometallic Chemistry of Rh-, Ir-, Pd-, and Pt-Based Radicals: Higher Valent Species. In: Karlin K.D. (red.), Progress in Inorganic Chemistry. Progress in Inorganic Chemistry nr. 55. Hoboken, NJ: John Wiley & Sons, Inc.. 247-354.
- Hetterscheid D.G.H., Hendriksen C., Dzik W.I., Smits J.M.M., Eck E.R.H. van, Rowan A.E., Busico V., Vacatello M., Axel Castelli V. van, Segre A., Jellema E., Bloemberg T.G. & Bruin B. de (2006), Rhodium-mediated stereoselective polymerization of "carbenes", Journal of the American Chemical Society 128(30): 9746-9752.
- Hetterscheid D.G.H. & Bruin B. de (2006), Open-shell rhodium and iridium species in (catalytic) oxygenation reactions, Journal of Molecular Catalysis A: Chemical 251(1-2): 291-296.
- Knijnenburg Q., Horton A.D., Heijden H. van der, Kooistra T.M., Hetterscheid D.G.H., Smits J.M.M., Bruin B. de, Budzelaar P.H.M. & Gal A.W. (2005), Olefin hydrogenation using diimine pyridine complexes of Co and Rh, Journal of Molecular Catalysis A: Chemical 232(1-2): 151-159.
- Hetterscheid D.G.H., Bens M. & Bruin B. de (2005), Ir-II(ethene): Metal or carbon radical? Part II: Oxygenation via iridium or direct oxygenation at ethene?, Dalton Transactions (5): 979-984.
- Hetterscheid D.G.H., Kaiser J., Reijerse E., Peters T.P.J., Thewissen S., Blok A.N.J., Smits J.M.M., Gelder R. de & Bruin B. de (2005), Ir-II(ethene): Metal or carbon radical?, Journal of the American Chemical Society 127(6): 1895-1905.
- Knijnenburg Q., Hetterscheid D., Kooistra T.M. & Budzelaar P.H.M. (2004), The electronic structure of (diiminopyridine)cobalt(I) complexes, European Journal of Inorganic Chemistry (6): 1204-1211.
- Hetterscheid D.G.H., Smits J.M.M. & Bruin B. de (2004), Chloride-triggered disproportionation of a mononuclear Rh-II(nbd) species to Rh-I(nbd) and Rh-III(eta(1)-norbornenyl) complexes: Possibilities for Wacker type mono-oxygenation of norbornadiene to norbornenone, Organometallics 23(18): 4236-4246.
- Kooistra T.M., Hetterscheid D.G.H., Schwartz E., Knijnenburg Q., Budzelaar P.H.M. & Gal A.W. (2004), Chemical ligand non-innocence in pyridine diimine Rh complexes, Inorganica Chimica Acta 357(10): 2945-2952.
- Beusker P.H., Veldhuis H., Brinkhorst J., Hetterscheid D.G.H., Feichter N., Bugaut A. & Scheeren H.W. (2003), Semisynthesis of 7-deoxypaclitaxel derivatives devoid of an oxetane D-ring, starting from taxine B, European Journal of Organic Chemistry 2003(4): 689-705.
- Hetterscheid D.G.H., Bruin B. de, Smits J.M.M. & Gal A.W. (2003), Disproportionation of Rh-II(cod) to Rh-I(cod) and Rh-III(cycloocta-2,5-dien-1-yl): Hydrogen atom transfer vs electron and proton transfer, Organometallics 22(15): 3022-3024.