Universiteit Leiden

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Dissertation

Graphene at fluidic interfaces

In this thesis unconventional tools based on fluidic interfaces were developed to study the surface and interfacial chemistry of graphene, to characterize the intrinsic properties of graphene, to disentangle the effects of substrate and of the environmental factors, and to improve handling protocols towards the preservation of the graphene cleanliness, morphology and electrical properties.

Author
Belyaeva, L.A.
Date
23 October 2019
Links
Thesis in Leiden Repository

In this thesis unconventional tools based on fluidic interfaces were developed to study the surface and interfacial chemistry of graphene, to characterize the intrinsic properties of graphene, to disentangle the effects of substrate and of the environmental factors, and to improve handling protocols towards the preservation of the graphene cleanliness, morphology and electrical properties.The use of liquid interfaces in graphene research is now emerging, and this thesis shows that the structural adaptability, molecular smoothness and weaker (compared to solids) intermolecular bonding of fluidic interfaces allow for experimental designs radically different from those involving solid substrates. By demonstrating that fluidic interfaces preserve graphene clean, smooth, unstrained and undoped, and by exploiting these advantages, a step forward was made to the design of (more) accessible and efficient graphene-based devices and technologies.

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